So far this seems to have gone pretty well with your manual, Nuxwin!
Web Services and i-MSCP are on the new server. The biggest trouble were getting Debian to use MySQL 5.7 instead of MariaDB (and finding/removing Marias leftovers preventing i-MSCP installation) and getting the plugins to work. The toupdate status did not cause the missing dependencies to be installed, instead touninstall, running tasks processer, then from the panel uninstalling those it missed, and reactivating one after the other did the trick.
I do have trouble with the i-MSCP service Lets Encrypt certs though. These were are still present from the old server and linkes to its hostname. If I click renew that won't work because Lets Encrypt expects the validation to be on the old server's hostname. I probably need to remove the existing certs from i-MSCP to have it request new ones instead. How can I do that?
The next thing that gives me a headache is switching the mailserver over. Rsyncing the contents worked well, but my old mailserver is running in dual stack mode and my DNS "mail." records (which is the target of my MX record) A and AAAA currently point to it. The server switch tutorial suggested using rinetd to redirect service requests to the new server. However rinetd does apparently not support IPv6. So if I stop Postfix and Dovecot and just setup the IPv4 redirect (while still having the old IPv6 mail record out there), will this work? Or will it lead to remote servers trying to deliver mails via IPv6 and failing miserably?
Thanks!